资源类型

期刊论文 230

会议视频 1

年份

2023 16

2022 21

2021 20

2020 18

2019 16

2018 8

2017 14

2016 12

2015 14

2014 10

2013 7

2012 9

2011 6

2010 6

2009 9

2008 16

2007 8

2006 5

2005 3

2004 3

展开 ︾

关键词

DX桩 2

人工智能 2

力学性能 2

单边直线感应电机 2

构件 2

沉降 2

COVID-19 1

Chebyshev多项式 1

Cu(In 1

CyTOF 1

DNA结构 1

Ga)Se2 1

LMS 1

Lagrange方程 1

PPP项目 1

SWOT分析 1

TMA 1

k-最近邻分类 1

一氧化碳 1

展开 ︾

检索范围：

排序： 展示方式：

Analysis of statistical thermodynamic model for binary protein adsorption equilibria on cation exchange

ZHOU Xiaopeng, SU Xueli, SUN Yan

《化学科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 103-112 doi: 10.1007/s11705-007-0020-x

摘要： A study of nonlinear competitive adsorption equilibria of proteins is of fundamental importance in understanding the behavior of preparative chromatographic separation. This work describes the nonlinear binary protein adsorption equilibria on ion exchangers by the statistical thermodynamic (ST) model. The single-component and binary protein adsorption isotherms of bovine hemoglobin (Hb) and bovine serum albumin (BSA) on SP Sepharose FF were determined by batch adsorption experiments in 0.05 mol/L sodium acetate buffer at three pH values (4.5, 5.0 and 5.5) and three NaCl concentrations (0.05, 0.10 and 0.15 mol/L) at pH 5.0. The ST model was found to depict the effects of pH and ionic strength on the single-component equilibria well, with model parameters depending on the pH and ionic strength. Moreover, the ST model gave acceptable fitting to the binary adsorption data with the fitted single-component model parameters, leading to the estimation of the binary ST model parameter. The effects of pH and ionic strength on the model parameters are reasonably interpreted by the electrostatic and thermodynamic theories. Results demonstrate the availability of the ST model for describing nonlinear competitive protein adsorption equilibria in the presence of two proteins.

关键词： fundamental importance     single-component equilibria     acceptable fitting     hemoglobin     chromatographic separation    

HTML PDF 收藏

Simulation studies on metastable phase equilibria in the aqueous ternary systems (NaCl-MgCl

Tianlong DENG, Baojun ZHANG, Dongchan LI, Yafei GUO

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 172-175 doi: 10.1007/s11705-009-0048-1

摘要： The solubilities and densities of the aqueous metastable ternary systems (NaCl-MgCl -H O) and (KCl-MgCl -H O) at 308.15 K were determined by the isothermal evaporation method. On the basis of the experimental results, the phase diagrams for those systems were plotted. It was found that the former system belongs to the hydrate-I type with one invariant point of (NaCl+ MgCl ?6H O), two univariant curves, and two crystallization regions corresponding to halite (NaCl) and bischofite (MgCl ·6H O); and the latter system belongs to the type of incongruent-double salts with two invariant points of (KCl+ KCl·MgCl ·6H O) and (MgCl ·6H O+ KCl·MgCl ·6H O), three univariant curves, and three crystallization regions corresponding to potassium chloride (KCl), carnallite (KCl·MgCl ·6H O) and bischofite (MgCl ·6H O). No solid solutions were found in both systems.

关键词： green chemistry     solar pond technique     simulation     metastable phase equilibrium     solubility    

HTML PDF 收藏

Preparation and permeability of ZSM-35 zeolite membranes on porous stainless steel tubes

ZHU Gang, WANG Jinqu, ZHANG Yan, LU Jinming, XIU Jinghai

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 217-220 doi: 10.1007/s11705-007-0039-z

摘要： ZSM-35 zeolite membranes were prepared on porous stainless steel tubes with silica sol and tetraethoxysilane as silica source, and with 1-butylamine and ethylenediamine as templates, respectively. The characterization of X-ray diffraction (XRD) and scanning electron microscopy (SEM) showed that the membranes prepared with ethylenediamine as the template displayed growth orientation with their crystal planes (h00) parallel to the support surface. The single-component permeability tests of H, N and CH showed that the membranes synthesized with ethylenediamine as the template, compared with those with 1-butylamine as the template, showed relatively higher permeation rates and ideal separation factors, and above their corresponding ideal Knudsen diffusion factors, which might be attributed to the different growth orientation of zeolite membranes synthesized with different templates.

关键词： single-component permeability     diffusion     different     permeation     orientation    

HTML PDF 收藏

An exploratory study for predicting component reliability with new load conditions

Zhengwei HU, Xiaoping DU

《机械工程前沿（英文）》 2019年 第14卷 第1期   页码 76-84 doi: 10.1007/s11465-018-0522-x

摘要： Reliability is important to design innovation. A new product should be not only innovative, but also reliable. For many existing components used in the new product, their reliability will change because the applied Loads are different from the ones for which the components are originally designed and manufactured. Then the new reliability must be re-evaluated. The system designers of the new product, however, may not have enough information to perform this task. With a beam problem as a case study, this study explores a feasible way to re-evaluate the component reliability with new Loads given the following information: The original reliability of the component with respect to the component Loads and the distributions of the new component Loads. Physics-based methods are employed to build the equivalent component limit-state function that can predict the component failure under the new Loads. Since the information is limited, the re-evaluated component reliability is given by its maximum and minimum values. The case study shows that good accuracy can be obtained even though the new reliability is provided with the aforementioned interval.

关键词： reliability     component     failure mode     prediction     random variable    

HTML PDF 收藏

Improved resilience measure for component recovery priority in power grids

《工程管理前沿（英文）》 2021年 第8卷 第4期   页码 545-556 doi: 10.1007/s42524-021-0161-5

摘要： Given the complexity of power grids, the failure of any component may cause large-scale economic losses. Consequently, the quick recovery of power grids after disasters has become a new research direction. Considering the severity of power grid disasters, an improved power grid resilience measure and its corresponding importance measures are proposed. The recovery priority of failed components after a disaster is determined according to the influence of the failed components on the power grid resilience. Finally, based on the data from the 2019 Power Yearbook of each city in Shandong Province, China, the power grid resilience after a disaster is analyzed for two situations, namely, partial components failure and failure of all components. Result shows that the recovery priorities of components with different importance measures vary. The resilience evaluations under different repair conditions prove the feasibility of the proposed method.

关键词： resilience measure     power grid     importance measure     component recovery    

HTML PDF 收藏

Molecular level simulations on multi-component systems —a morphology prediction method

C. SCHMIDT, J. ULRICH

《化学科学与工程前沿（英文）》 2013年 第7卷 第1期   页码 49-54 doi: 10.1007/s11705-013-1307-8

摘要： The crystal morphology grown from a solution composed of an organic solvent, solute and additive can be predicted reliably by a computational method. Modeling the supersaturated solution as liquid phase is achieved by employing commercial software. The molecular composition of this solution is a required input parameter. The face specific diffusion coefficient of the solid (crystal surface) and liquid (solution) system is determined using the molecular dynamics procedure. The obtained diffusion coefficient is related to the specific face growth rate via the attachment energy of the pure morphology. The significant improvements are achieved in the morphology prediction because the investigation on the face growth rates in a complex growth environment (as multi-component solutions with additives) can be carried out based on the diffusion coefficients.

关键词： crystallization     morphology     molecular dynamics     solution    

HTML PDF 收藏

Robust optimization of the billet for isothermal local loading transitional region of a Ti-alloy rib-web component

Ke WEI, Xiaoguang FAN, Mei ZHAN, Miao MENG

《机械工程前沿（英文）》 2018年 第13卷 第3期   页码 376-384 doi: 10.1007/s11465-018-0500-3

摘要：

Billet optimization can greatly improve the forming quality of the transitional region in the isothermal local loading forming (ILLF) of large-scale Ti-alloy rib-web components. However, the final quality of the transitional region may be deteriorated by uncontrollable factors, such as the manufacturing tolerance of the preforming billet, fluctuation of the stroke length, and friction factor. Thus, a dual-response surface method (RSM)-based robust optimization of the billet was proposed to address the uncontrollable factors in transitional region of the ILLF. Given that the die underfilling and folding defect are two key factors that influence the forming quality of the transitional region, minimizing the mean and standard deviation of the die underfilling rate and avoiding folding defect were defined as the objective function and constraint condition in robust optimization. Then, the cross array design was constructed, a dual-RSM model was established for the mean and standard deviation of the die underfilling rate by considering the size parameters of the billet and uncontrollable factors. Subsequently, an optimum solution was derived to achieve the robust optimization of the billet. A case study on robust optimization was conducted. Good results were attained for improving the die filling and avoiding folding defect, suggesting that the robust optimization of the billet in the transitional region of the ILLF was efficient and reliable.

关键词： isothermal local loading forming     rib-web component     transitional region     robust optimization     dual response surface method    

HTML PDF 收藏

Development of a multi-component drug from turmeric using central composite design

Xiaohang ZHANG,Shengnan HAN,Yan LI,Jianlan JIANG

《化学科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 362-368 doi: 10.1007/s11705-014-1439-5

摘要： A methodology to develop multi-component drugs based on traditional Chinese medicines has been developed using central composite design. Several active components from the traditional Chinese medicine turmeric were chosen for use in a multi-component antitumor drug. Response surface methodology based on a central composite design was applied to determine the quantitative composition-activity relationships in order to optimize the amount of each component in the drug. An MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) assay was used to measure the pharmacological activity as the response value. The experimental antitumor activity of the optimum combination was 92.85% in the MTT assay and superior to the activities of each single component. These results demonstrate that response surface methodology based on a central composite design is suitable for the design of multi-component drugs.

关键词： multi-component drug development     central composite design     turmeric     curcuminoids    

HTML PDF 收藏

Non-negativematrix factorization based unmixing for principal component transformed hyperspectral data

Xiu-rui GENG,Lu-yan JI,Kang SUN

《信息与电子工程前沿（英文）》 2016年 第17卷 第5期   页码 403-412 doi: 10.1631/FITEE.1600028

摘要： Non-negative matrix factorization (NMF) has been widely used in mixture analysis for hyperspectral remote sensing. When used for spectral unmixing analysis, however, it has two main shortcomings: (1) since the dimensionality of hyperspectral data is usually very large, NMF tends to suffer from large computational complexity for the popular multiplicative iteration rule; (2) NMF is sensitive to noise (outliers), and thus the corrupted data will make the results of NMF meaningless. Although principal component analysis (PCA) can be used to mitigate these two problems, the transformed data will contain negative numbers, hindering the direct use of the multiplicative iteration rule of NMF. In this paper, we analyze the impact of PCA on NMF, and find that multiplicative NMF can also be applicable to data after principal component transformation. Based on this conclusion, we present a method to perform NMF in the principal component space, named ‘principal component NMF’ (PCNMF). Experimental results show that PCNMF is both accurate and time-saving.

关键词： Non-negative matrix factorization (NMF)     Principal component analysis (PCA)     Endmember     Hyperspectral    

HTML PDF 收藏

of cutting parameters in high-speed milling based on grey relational analysis coupled with principal component

Tao FU, Jibin ZHAO, Weijun LIU

《机械工程前沿（英文）》 2012年 第7卷 第4期   页码 445-452 doi: 10.1007/s11465-012-0338-z

摘要：

This paper investigates optimization problem of the cutting parameters in high-speed milling on NAK80 mold steel. An experiment based on the technology of Taguchi is performed. The objective is to establish a correlation among spindle speed, feed per tooth and depth of cut to the three directions of cutting force in the milling process. In this study, the optimum cutting parameters are obtained by the grey relational analysis. Moreover, the principal component analysis is applied to evaluate the weights so that their relative significance can be described properly and objectively. The results of experiments show that grey relational analysis coupled with principal component analysis can effectively acquire the optimal combination of cutting parameters and the proposed approach can be a useful tool to reduce the cutting force.

关键词： high-speed milling     grey relational analysis     principal component analysis     parameters optimization    

HTML PDF 收藏

银行国际贸易结算系统构件化设计与实现

余金山,陈志强

《中国工程科学》 2004年 第6卷 第9期   页码 81-87

摘要：

国际贸易结算是银行业中一种必不可少的业务，占据着重要的地位，而且随着电子商务的发展，其重要性也越来越突出。但是，这一业务的计算机化相当困难。主要原因是：操作流程复杂；组合变化太多，对灵活性有很高要求；涉及面相当广，几乎涉及银行的每一个业务品种，是一个压缩版的银行系统。因此，开发这样的系统必须采用先进的而且较为合适的方法和技术。文章提出了以构建半成品构件系统为总体思想的开发方法；在设计和实现上，提出了以数据总线为统一接口，以菜单/功能图标为总控主体框架，以基本业务操作为基本组件，并能把基本组件包装裁剪成可在主体框架控制下运行的功能构件，这样构建的系统可按实际需要进行组装、剪裁、参数设定、重新包装或经少量改写而形成一个实际可运行的系统。并提供了与银行总系统集成的灵活接口，具备了向网上银行和分布系统发展的良好基础。

关键词： 银行     国际贸易结算系统     构件     半成品系统    

HTML PDF 收藏

removal of ocular artifacts from electroencephalogram signals using spatial constraint independent component

Bang-hua YANG,Liang-fei HE,Lin LIN,Qian WANG

《信息与电子工程前沿（英文）》 2015年 第16卷 第6期   页码 486-496 doi: 10.1631/FITEE.1400299

摘要： Ocular artifacts cause the main interfering signals within electroencephalogram (EEG) signal measurements. An adaptive filter based on reference signals from an electrooculogram (EOG) can reduce ocular interference, but collecting EOG signals during a long-term EEG recording is inconvenient and uncomfortable for the subject. To remove ocular artifacts from EEG in brain-computer interfaces (BCIs), a method named spatial constraint independent component analysis based recursive least squares (SCICA-RLS) is proposed. The method consists of two stages. In the first stage, independent component analysis (ICA) is used to decompose multiple EEG channels into an equal number of independent components (ICs). Ocular ICs are identified by an automatic artifact detection method based on kurtosis. Then empirical mode decomposition (EMD) is employed to remove any cerebral activity from the identified ocular ICs to obtain exact artifact ICs. In the second stage, first, SCICA applies exact artifact ICs obtained in the first stage as a constraint to extract artifact ICs from the given EEG signal. These extracted ICs are called spatial constraint ICs (SC-ICs). Then the RLS based adaptive filter uses SC-ICs as reference signals to reduce interference, which avoids the need for parallel EOG recordings. In addition, the proposed method has the ability of fast computation as it is not necessary for SCICA to identify all ICs like ICA. Based on the EEG data recorded from seven subjects, the new approach can lead to average classification accuracies of 3.3% and 12.6% higher than those of the standard ICA and raw EEG, respectively. In addition, the proposed method has 83.5% and 83.8% reduction in time-consumption compared with the standard ICA and ICA-RLS, respectively, which demonstrates a better and faster OA reduction.

关键词： Ocular artifacts     Electroencephalogram (EEG)     Electrooculogram (EOG)     Brain-computer interface (BCI)     Spatial constraint independent component analysis based recursive least squares (SCICA-RLS)    

HTML PDF 收藏

Crystallographic orientation effect on cutting-based single atomic layer removal

Wenkun XIE, Fengzhou FANG

《机械工程前沿（英文）》 2020年 第15卷 第4期   页码 631-644 doi: 10.1007/s11465-020-0599-x

摘要： The ever-increasing requirements for the scalable manufacturing of atomic-scale devices emphasize the significance of developing atomic-scale manufacturing technology. The mechanism of a single atomic layer removal in cutting is the key basic theoretical foundation for atomic-scale mechanical cutting. Material anisotropy is among the key decisive factors that could not be neglected in cutting at such a scale. In the present study, the crystallographic orientation effect on the cutting-based single atomic layer removal of monocrystalline copper is investigated by molecular dynamics simulation. When undeformed chip thickness is in the atomic scale, two kinds of single atomic layer removal mechanisms exist in cutting-based single atomic layer removal, namely, dislocation motion and extrusion, due to the differing atomic structures on different crystallographic planes. On close-packed crystallographic plane, the material removal is dominated by the shear stress-driven dislocation motion, whereas on non-close packed crystallographic planes, extrusion-dominated material removal dominates. To obtain an atomic, defect-free processed surface, the cutting needs to be conducted on the close-packed crystallographic planes of monocrystalline copper.

关键词： ACSM     single atomic layer removal mechanism     crystallographic orientation effect     mechanical cutting     Manufacturing III    

HTML PDF 收藏

Design and analysis of partially decoupled translational parallel mechanisms with single-loop structures

《机械工程前沿（英文）》 2022年 第17卷 第3期 doi: 10.1007/s11465-022-0695-1

摘要： This study presents a family of novel translational parallel mechanisms (TPMs) with single-loop topological structures. The proposed mechanism consists of only revolute and prismatic joints. The novel TPMs are simpler in structure and have fewer joints and components than the well-known Delta Robot. Four types of 2-degree of freedom driving systems are applied to different limb structures to avoid the moving actuator that causes the problem of increased moving mass. Four sample TPMs are constructed using the synthesized limbs, and one of them is investigated in terms of kinematic performance. First, a position analysis is performed and validated through numerical simulation to reveal the characteristics of partially decoupled motion, which improves the controllability of TPM. Second, singular configurations are identified, and the resulting singularity curve is obtained. Lastly, the workspace of TPM is analyzed, and the relationship between the singular configurations and the reachable workspace is explored. The workspace of the 3-CRR (C denotes the cylindrical joint and R denotes the revolute joint) translational mechanism is also presented to prove that the proposed TPM has a fairly large workspace.

关键词： translational parallel mechanism     single loop     multiple driving system     workspace analysis     singularity    

HTML PDF 收藏

One-pot three-component Mannich reaction catalyzed by sucrose char sulfonic acid

Qiong XU, Zhigao YANG, Dulin YIN, Jihui WANG

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 201-205 doi: 10.1007/s11705-009-0052-5

摘要： Sucrose char sulfonic acid efficiently catalyzed the one-pot three-component Mannich reaction of ketones, aromatic aldehydes and amines in ethanol to afford the corresponding -amino carbonyl compounds in good to excellent yields. A series of heteroaromatic -amino carbonyl compounds can be obtained when using 2-acetylpyrazine as substrate. This reaction can be performed under mild reaction conditions with clean reaction profiles and a simple workup procedure.

关键词： One–pot synthesis     b-amino ketone     char sulfonic acid     2-acetylpyrazine     catalysis    

HTML PDF 收藏

标题 作者 时间 类型 操作

Analysis of statistical thermodynamic model for binary protein adsorption equilibria on cation exchange

ZHOU Xiaopeng, SU Xueli, SUN Yan

期刊论文

Simulation studies on metastable phase equilibria in the aqueous ternary systems (NaCl-MgCl

Tianlong DENG, Baojun ZHANG, Dongchan LI, Yafei GUO

期刊论文

Preparation and permeability of ZSM-35 zeolite membranes on porous stainless steel tubes

ZHU Gang, WANG Jinqu, ZHANG Yan, LU Jinming, XIU Jinghai

期刊论文

An exploratory study for predicting component reliability with new load conditions

Zhengwei HU, Xiaoping DU

期刊论文

Improved resilience measure for component recovery priority in power grids

期刊论文

Molecular level simulations on multi-component systems —a morphology prediction method

C. SCHMIDT, J. ULRICH

期刊论文

Robust optimization of the billet for isothermal local loading transitional region of a Ti-alloy rib-web component

Ke WEI, Xiaoguang FAN, Mei ZHAN, Miao MENG

期刊论文

Development of a multi-component drug from turmeric using central composite design

Xiaohang ZHANG,Shengnan HAN,Yan LI,Jianlan JIANG

期刊论文

Non-negativematrix factorization based unmixing for principal component transformed hyperspectral data

Xiu-rui GENG,Lu-yan JI,Kang SUN

期刊论文

of cutting parameters in high-speed milling based on grey relational analysis coupled with principal component

Tao FU, Jibin ZHAO, Weijun LIU

期刊论文

银行国际贸易结算系统构件化设计与实现

余金山,陈志强

期刊论文

removal of ocular artifacts from electroencephalogram signals using spatial constraint independent component

Bang-hua YANG,Liang-fei HE,Lin LIN,Qian WANG

期刊论文

Crystallographic orientation effect on cutting-based single atomic layer removal

Wenkun XIE, Fengzhou FANG

期刊论文

Design and analysis of partially decoupled translational parallel mechanisms with single-loop structures

期刊论文

One-pot three-component Mannich reaction catalyzed by sucrose char sulfonic acid

Qiong XU, Zhigao YANG, Dulin YIN, Jihui WANG

期刊论文